How to Calculate Rate of Diffusion Across a Membrane

Rate of Diffusion Calculator (Fick's Law) :root { –primary-color: #2c3e50; –secondary-color: #3498db; –accent-color: #e74c3c; –light-bg: #f8f9fa; –border-radius: 8px; } body { font-family: -apple-system, BlinkMacSystemFont, "Segoe UI", Roboto, Helvetica, Arial, sans-serif; line-height: 1.6; color: #333; margin: 0; padding: 20px; } .calculator-container { max-width: 800px; margin: 0 auto; background: #fff; padding: 30px; border-radius: var(–border-radius); box-shadow: 0 4px 15px rgba(0,0,0,0.1); } .calc-header { text-align: center; margin-bottom: 30px; border-bottom: 2px solid var(–light-bg); padding-bottom: 20px; } .calc-header h2 { color: var(–primary-color); margin: 0; } .input-grid { display: grid; grid-template-columns: 1fr 1fr; gap: 20px; } @media (max-width: 600px) { .input-grid { grid-template-columns: 1fr; } } .form-group { margin-bottom: 15px; } .form-group label { display: block; margin-bottom: 5px; font-weight: 600; color: var(–primary-color); } .form-group input { width: 100%; padding: 10px; border: 1px solid #ddd; border-radius: 4px; font-size: 16px; box-sizing: border-box; } .form-group input:focus { border-color: var(–secondary-color); outline: none; } .form-group .unit-hint { font-size: 0.85em; color: #666; margin-top: 4px; } .calc-btn { width: 100%; padding: 12px; background-color: var(–secondary-color); color: white; border: none; border-radius: 4px; font-size: 18px; font-weight: bold; cursor: pointer; transition: background 0.2s; margin-top: 10px; } .calc-btn:hover { background-color: #2980b9; } .result-section { margin-top: 30px; padding: 20px; background-color: var(–light-bg); border-radius: var(–border-radius); border-left: 5px solid var(–secondary-color); display: none; } .result-title { font-size: 1.1em; font-weight: bold; color: var(–primary-color); margin-bottom: 10px; } .result-value { font-size: 2em; color: var(–secondary-color); font-weight: bold; } .error-msg { color: var(–accent-color); font-weight: bold; margin-top: 10px; display: none; } .article-content { max-width: 800px; margin: 40px auto; padding: 20px; background: #fff; } .article-content h2 { color: var(–primary-color); border-bottom: 2px solid var(–secondary-color); padding-bottom: 10px; margin-top: 30px; } .article-content h3 { color: var(–primary-color); margin-top: 25px; } .article-content ul { background: var(–light-bg); padding: 20px 40px; border-radius: 8px; } .article-content li { margin-bottom: 10px; } .formula-box { background: #f1f8ff; padding: 15px; border-radius: 5px; font-family: 'Courier New', monospace; text-align: center; margin: 20px 0; font-weight: bold; border: 1px dashed var(–secondary-color); }

Fick's Law Diffusion Calculator

Calculate the rate of diffusion across a membrane based on surface area, concentration gradient, and thickness.

Area per unit time (e.g., cm²/s)
Area of membrane (e.g., cm²)
Higher concentration (e.g., mol/cm³)
Lower concentration (e.g., mol/cm³)
Distance of diffusion path (e.g., cm)
Estimated Rate of Diffusion (J):
0
Units: Amount per unit time (based on your inputs)

Concentration Gradient (ΔC): 0
Diffusion Efficiency: 0

function calculateDiffusion() { var D = document.getElementById("diffCoef").value; var A = document.getElementById("surfArea").value; var C1 = document.getElementById("conc1").value; var C2 = document.getElementById("conc2").value; var d = document.getElementById("thickness").value; var errorDiv = document.getElementById("errorMsg"); var resultDiv = document.getElementById("resultSection"); // Reset display errorDiv.style.display = "none"; resultDiv.style.display = "none"; // Validation if (D === "" || A === "" || C1 === "" || C2 === "" || d === "") { errorDiv.innerText = "Please fill in all fields."; errorDiv.style.display = "block"; return; } var numD = parseFloat(D); var numA = parseFloat(A); var numC1 = parseFloat(C1); var numC2 = parseFloat(C2); var numDThickness = parseFloat(d); if (isNaN(numD) || isNaN(numA) || isNaN(numC1) || isNaN(numC2) || isNaN(numDThickness)) { errorDiv.innerText = "Please enter valid numbers."; errorDiv.style.display = "block"; return; } if (numDThickness === 0) { errorDiv.innerText = "Membrane thickness cannot be zero."; errorDiv.style.display = "block"; return; } if (numD < 0 || numA < 0 || numDThickness < 0) { errorDiv.innerText = "Coefficient, Area, and Thickness must be positive numbers."; errorDiv.style.display = "block"; return; } // Calculation: Fick's Law J = (D * A * (C1 – C2)) / d // We use Math.abs for concentration difference to ensure magnitude of rate is positive var deltaC = Math.abs(numC1 – numC2); var rate = (numD * numA * deltaC) / numDThickness; // Display results document.getElementById("diffusionResult").innerText = rate.toExponential(4); // Scientific notation for precision document.getElementById("gradientResult").innerText = deltaC.toFixed(4); // Efficiency metric (Rate per unit area) var efficiency = rate / numA; document.getElementById("efficiencyResult").innerText = efficiency.toExponential(4) + " / area unit"; resultDiv.style.display = "block"; }

How to Calculate Rate of Diffusion Across a Membrane

Diffusion is a fundamental process in biology, physics, and chemistry, describing the net movement of molecules from an area of higher concentration to an area of lower concentration. When this process occurs across a permeable membrane—such as a cell membrane or a synthetic filter—the rate of this movement can be quantified using Fick's First Law of Diffusion.

Fick's Law Formula

The rate of diffusion ($J$) is determined by several key factors: the permeability of the membrane to the specific substance, the surface area available for transport, the concentration difference, and the thickness of the membrane. The mathematical representation is:

J = (D × A × ΔC) / d

Where:

  • J (Rate of Diffusion): The amount of substance moving across the membrane per unit of time (e.g., mol/s).
  • D (Diffusion Coefficient): A constant representing how easily a specific substance moves through a specific medium. This depends on temperature, the size of the molecule, and the viscosity of the fluid.
  • A (Surface Area): The total area of the membrane available for diffusion. A larger area allows more molecules to pass through simultaneously.
  • ΔC (Concentration Gradient): The difference in concentration between the two sides of the membrane ($C_1 – C_2$). The steeper the gradient, the faster the diffusion.
  • d (Thickness): The distance the molecules must travel. A thicker membrane slows down the rate of diffusion.

Example Calculation

Let's look at a practical example involving oxygen diffusion across a theoretical respiratory membrane.

Parameters:

  • Diffusion Coefficient ($D$): $2.0 \times 10^{-5} \, \text{cm}^2/\text{s}$
  • Surface Area ($A$): $50 \, \text{cm}^2$
  • Concentration High ($C_1$): $0.005 \, \text{mol/cm}^3$
  • Concentration Low ($C_2$): $0.001 \, \text{mol/cm}^3$
  • Membrane Thickness ($d$): $0.0002 \, \text{cm}$

Step 1: Calculate the Concentration Gradient ($ΔC$)
$ΔC = 0.005 – 0.001 = 0.004 \, \text{mol/cm}^3$

Step 2: Apply Fick's Law
Numerator = $D \times A \times ΔC$
Numerator = $(2.0 \times 10^{-5}) \times 50 \times 0.004$
Numerator = $4.0 \times 10^{-6}$

Step 3: Divide by Thickness
$J = 4.0 \times 10^{-6} / 0.0002$
$J = 0.02 \, \text{mol/s}$

Factors Affecting Diffusion Rate

Understanding these variables helps in various fields, from drug delivery systems to environmental engineering.

  1. Membrane Thickness: This is inversely proportional to the rate. This is why respiratory surfaces in lungs (alveoli) are extremely thin—to maximize gas exchange.
  2. Surface Area: Directly proportional. Microvilli in the human intestine increase surface area drastically to aid nutrient absorption.
  3. Concentration Gradient: The driving force of simple diffusion. Without a difference in concentration, net diffusion is zero.
  4. Temperature: While not a direct input in the simplified formula above, temperature affects the Diffusion Coefficient ($D$). Higher temperatures increase molecular kinetic energy, increasing $D$ and thus the rate of diffusion.

Unit Consistency

When using the calculator above, it is critical to ensure your units are consistent. If your Area is in $m^2$, your Diffusion Coefficient should be in $m^2/s$, your Concentration in $mol/m^3$, and your Thickness in $m$. Mixing units (e.g., cm for thickness but meters for area) will result in incorrect calculations unless manually converted beforehand.

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